MSDS Number: ALUSD * * * * * Effective Date: 12/15/08 * * * * * Supercedes: 06/16/03 ALUMINUM STEARATE


ALUMINUM STEARATE


1. Product Identification

Synonyms: Aluminum distearate
CAS No.: 300-92-5
Molecular Weight: 610.9
Chemical Formula: C36H71O5 Al
Product Codes: 2222, 2235, 2658, 3891, 4678, 4811, 5501, 5503, 5589

2. Composition/Information on Ingredients


  Ingredient                                CAS No         Percent        Hazardous                                  
  ---------------------------------------   ------------   ------------   ---------   
 
  Aluminum Stearate                         300-92-5           100%          Yes                                                                 
  The exact product composition depends on the source and purity of the fatty 
  acid used.
 

3. Hazards Identification

Emergency Overview
--------------------------
WARNING! MAY FORM COMBUSTIBLE DUST CONCENTRATIONS IN AIR.

Potential Health Effects
----------------------------------

Inhalation:
Symptoms from excessive inhalation of dust may include coughing and difficult breathing.
Ingestion:
Low level of toxicity by ingestion.
Skin Contact:
No information found. Not expected to be a hazard.
Eye Contact:
May cause mechanical irritation.
Chronic Exposure:
Grossly excessive and chronic inhalation of the dust may cause a progressive chemical pneumonitis, cyanosis, and pulmonary edema.

Aggravation of Pre-existing Conditions:
Persons with pre-existing skin disorders, impaired respiratory function, or a history of pulmonary disease should not be exposed to dusts.

4. First Aid Measures

Inhalation:
Remove to fresh air. Get medical attention for any breathing difficulty.
Ingestion:
Give several glasses of water to drink to dilute. If large amounts were swallowed, get medical advice.
Skin Contact:
Wash exposed area with soap and water. Get medical advice if irritation develops.
Eye Contact:
Wash thoroughly with running water. Get medical advice if irritation develops.

5. Fire Fighting Measures

Fire:
As with most organic solids, fire is possible at elevated temperatures or by contact with an ignition source. Minimum dust cloud ignition temperature: 670C (1238F).
Explosion:
Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard. Maximum explosion pressure : 65 lb/sq. in. @ 0.2 oz./cu. ft.
Fire Extinguishing Media:
Water spray, dry chemical, alcohol foam, or carbon dioxide. Water or foam may cause frothing.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. Pressure from the extinguishing media may cause severe dusting. Melted fatty acid can give "grease" type fire. Actual temperatures and concentrations may vary by product composition.

6. Accidental Release Measures

Remove all sources of ignition. Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Clean up spills in a manner that does not disperse dust into the air. Use non-sparking tools and equipment. Reduce airborne dust and prevent scattering by moistening with water. Pick up spill for recovery or disposal and place in a closed container.

7. Handling and Storage

Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Avoid dust formation and control ignition sources. Employ grounding, venting and explosion relief provisions in accord with accepted engineering practices in any process capable of generating dust and/or static electricity. Empty only into inert or non-flammable atmosphere. Emptying contents into a non-inert atmosphere where flammable vapors may be present could cause a flash fire or explosion due to electrostatic discharge. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits:
-OSHA Permissible Exposure Limit (PEL):
15 mg/m3 total dust, 5 mg/m3 respirable fraction for nuisance dusts.
-ACGIH Threshold Limit Value (TLV):
10 mg/m3 total dust for stearates (does not include stearates of toxic metals) A4 - Not classifiable as a Human Carcinogen.
Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved):
If the exposure limit is exceeded, a half-face dust/mist respirator may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full-face piece dust/mist respirator may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection:
Gloves and lab coat, apron or coveralls.
Eye Protection:
Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area.

9. Physical and Chemical Properties

Appearance:
Fine white to off-white powder.
Odor:
Slight odor of fatty acid.
Solubility:
Insoluble in water; soluble in benzene, alcohol.
Specific Gravity:
1.01
pH:
No information found.
% Volatiles by volume @ 21C (70F):
No information found.
Boiling Point:
Decomposes.
Melting Point:
150 - 165C (302 - 329F)
Vapor Density (Air=1):
No information found.
Vapor Pressure (mm Hg):
No information found.
Evaporation Rate (BuAc=1):
No information found.

10. Stability and Reactivity

Stability:
Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products:
Carbon dioxide and carbon monoxide may form when heated to decomposition.
Hazardous Polymerization:
Will not occur.
Incompatibilities:
No information found.
Conditions to Avoid:
No information found.

11. Toxicological Information

  --------\Cancer Lists\------------------------------------------------------
                                         ---NTP Carcinogen---
  Ingredient                             Known    Anticipated    IARC Category
  ------------------------------------   -----    -----------    -------------
  Aluminum Stearate (300-92-5)            No          No            None

12. Ecological Information

Environmental Fate:
No information found.
Environmental Toxicity:
No information found.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

14. Transport Information

Not regulated.

15. Regulatory Information

EU data:
EINECS # 206-101-8
R36/37/38 - Irritating to eyes, respiratory system and skin.
S22/24/25 - Do not breath dust, avoid contact with skin and eyes.

  --------\Chemical Inventory Status - Part 1\---------------------------------
  Ingredient                                       TSCA  EC   Japan  Australia
  -----------------------------------------------  ----  ---  -----  ---------
  Aluminum Stearate (300-92-5)                      Yes  Yes   Yes      Yes                                      
 
  --------\Chemical Inventory Status - Part 2\---------------------------------
                                                          --Canada--
  Ingredient                                       Korea  DSL   NDSL  Phil.
  -----------------------------------------------  -----  ---   ----  -----
  Aluminum Stearate (300-92-5)                      Yes   Yes   No     Yes         
 
  --------\Federal, State & International Regulations - Part 1\----------------
                                             -SARA 302-    ------SARA 313------
  Ingredient                                 RQ    TPQ     List  Chemical Catg.
  -----------------------------------------  ---   -----   ----  --------------
  Aluminum Stearate (300-92-5)               No    No      No         No
 
  --------\Federal, State & International Regulations - Part 2\----------------
                                                        -RCRA-    -TSCA-
  Ingredient                                 CERCLA     261.33     8(d) 
  -----------------------------------------  ------     ------    ------
  Aluminum Stearate (300-92-5)               No         No         No       
 
 
Chemical Weapons Convention:  No     TSCA 12(b):  No     CDTA:  No
SARA 311/312:  Acute: No       Chronic: No   Fire: Yes Pressure: No
Reactivity: No          (Pure / Solid) 


Australian Hazchem Code: None allocated.
Poison Schedule: None allocated.
WHMIS:
This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.

16. Other Information

NFPA Ratings: Health: 0 Flammability: 1 Reactivity: 0
Label Hazard Warning:
WARNING! MAY FORM COMBUSTIBLE DUST CONCENTRATIONS IN AIR.
Label Precautions:
Avoid breathing dust.
Store in a tightly closed container.
Avoid dust cloud in presence of an ignition source.
Maintain adequate ventilation.
As part of good industrial and personal hygiene and safety procedure, avoid all unnecessary exposure to the chemical substance and ensure prompt removal from skin, eyes and clothing.
Label First Aid:
If inhaled, remove to fresh air. Get medical attention for any breathing difficulty. If large amounts were swallowed, give water to drink and get medical advice. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes. Get medical attention if irritation develops or persists.
Product Use:
This product has diverse use in chemical manufacturing and processing.
Revision Information:
MSDS Section(s) changed since last revision of document include: 3, 15.
Disclaimer:
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Mallinckrodt provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. MALLINCKRODT MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, MALLINCKRODT WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION.
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Prepared by: Environmental Health & Safety
Phone Number: (314) 654-1600 (U.S.A.)